metal-organic frameworks to metal/metal oxide embedded carbon matrix: synthesis, characterization and gas sorption properties
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ID: 214027
2015
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Abstract
Three isostructural metal-organic frameworks, (MOFs), [Fe(OH)(1,4-NDC)] (1), [Al(OH)(1,4-NDC)] (2), and [In(OH)(1,4-NDC)] (3) have been synthesized hydrothermally by using 1,4-naphthalene dicarboxylate (1,4-NDC) as a linker. The MOFs were characterized using various techniques and further used as precursor materials for the synthesis of metal/metal oxide nanoparticles inserted in a carbon matrix through a simple thermal conversion method. The newly synthesized carbon materials were characterized by scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy analysis, powder X-ray diffraction and BET analysis. The results showed that the MOF-derived carbon composite materials maintained the morphology of the original MOF upon carbonization, and confirmed the insertion of metal/metal oxide particles in the carbon matrix.
| Reference Key |
chen2015materialsmetal-organic
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| Authors | ;Jiun-Jen Chen;Ya-Ting Chen;Duraisamy Senthil Raja;Yu-Hao Kang;Pen-Chang Tseng;Chia-Her Lin |
| Journal | Nature Materials |
| Year | 2015 |
| DOI |
10.3390/ma8085245
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