preparation and characterization of new inclusion compounds using stable nitroxide radicals and an organic 1-d nanochannel as a template

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2010
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Abstract
A new inclusion compound (IC) using di-t-buthyl nitroxide (DBNO) radical and tris(o-phenylenedioxy)cyclotriphosphazene (TPP) (1), which has an organic one-dimensional (1-D) nanochannel in the crystal, is reported. According to the characterization using thermogravimetric analysis (TG), ESR measurements, etc., the composition of the inclusion compound was assigned as TPP:DBNO = 1:0.62. The narrowing of the isotropic ESR adsorption line of 1 was observed with a temperature increase from 103 K to room temperature. The line shape indicated a type of 1-D spin diffusion as observed in our previous study of the IC using TPP and 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO).
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Authors ;Hirokazu Kobayashi;Tetsuo Asaji;Atsushi Tani
Journal Nature Materials
Year 2010
DOI
10.3390/ma3063625
URL
http://www.mdpi.com/1996-1944/3/6/3625/
Keywords
esr tpp electronics civil engineering (general)microscopydescriptive and experimental mechanics nuclear engineeringengineering (general)

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