Solvent-controlled selective synthesis of biphenols and quinones via oxidative coupling of phenols.

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ID: 263122
2017
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Ranked #29 of 184 articles by views in Chemical communications (Cambridge, England)

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Abstract
A regioselective synthesis of unsymmetrical and symmetrical biphenols and binaphthols via oxidative coupling of phenols or naphthols in the presence of KSO in CFCOOH under ambient conditions is described. Interestingly, the 1 : 1 ratio of HO and CHCN solvent mixtures at 80 °C instead of CFCOOH provided substituted unsymmetrical quinones. A gram-scale synthesis of biphenols and binaphthols was demonstrated.
Reference Key
more2017solventcontrolledchemical Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors More, Nagnath Yadav;Jeganmohan, Masilamani;
Journal Chemical communications (Cambridge, England)
Year 2017
DOI
10.1039/c7cc04829g
URL
Keywords
antioxidants nos2 ho-1 cox-2 raw264.7 cells eugenol-related compounds theoretical parameters

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