metal complexes of schiff’s bases derived from 3-(arylazo)-2,4-pentanediones with 2-aminophenol and 2-aminothiophenol
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ID: 140164
2007
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Abstract
Phenylazo- and thiazolylazo-2,4-pentanediones on reaction with 2-aminophenol and 2-aminothiophenol yielded a new series of polydentate Schiff’s base ligands. The structure and tautomeric nature of these compounds and their metal complexes were established on the basis of their IR, 1H-NMR and mass spectral data. The spectral and analytical data revealed the condensation of both carbonyl groups of 3-(2-thiazolylazo)- 2,4-pentanedione with 2-aminophenol to form an N2O2 tetradentate ligand. Details on the formation of its [ML] complexes with Ni(II), Cu(II) and Zn(II) and the nature of their bonding are discussed based on analytical, IR, 1H-NMR and mass spectral data.
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krishnankutty2007journalmetal
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| Authors | ;K. KRISHNANKUTTY;P. SAYUDEVI;MUHAMMED BASHEER UMMATHUR |
| Journal | meditsinskaia radiologiia |
| Year | 2007 |
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