Nickel(ii)-methyl complexes adopting unusual seesaw geometries.

Clicks: 222
ID: 92625
2020
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Abstract
We report four-coordinate nickel(ii)-methyl complexes of tris-carbene borate ligands which adopt rare seesaw geometries. Experimental and computational results suggest the structural distortion from threefold symmetry results from a combination of electronic stabilization of the singlet state, strong field donors, and constrained angles from the chelating ligand.
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hill2020nickeliimethylchemical Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Hill, Ethan A;Zhao, Norman;Filatov, Alexander S;Anderson, John S;
Journal Chemical communications (Cambridge, England)
Year 2020
DOI
10.1039/c9cc09249h
URL
Keywords
amine-imine-exchange strategy morphological transformation orthogonal dynamic covalent self-assembly polymer nanocapsules and thin films

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