Nickel(ii)-methyl complexes adopting unusual seesaw geometries.

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ID: 92625
2020
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Ranked #91 of 184 articles by views in Chemical communications (Cambridge, England)

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Abstract
We report four-coordinate nickel(ii)-methyl complexes of tris-carbene borate ligands which adopt rare seesaw geometries. Experimental and computational results suggest the structural distortion from threefold symmetry results from a combination of electronic stabilization of the singlet state, strong field donors, and constrained angles from the chelating ligand.
Reference Key
hill2020nickeliimethylchemical Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Hill, Ethan A;Zhao, Norman;Filatov, Alexander S;Anderson, John S;
Journal Chemical communications (Cambridge, England)
Year 2020
DOI
10.1039/c9cc09249h
URL
Keywords
amine-imine-exchange strategy morphological transformation orthogonal dynamic covalent self-assembly polymer nanocapsules and thin films

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