Ag(μ-S)(p-TBBT)(PPh): symmetry breaking induced by the core to generate chirality.

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ID: 92624
2020
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Abstract
A chiral silver-sulfur nanocluster with a μ8-S inside, Ag18(μ8-S)(p-TBBT)16(PPh3)8, was successfully synthesized and characterized. This nanocluster is composed of a crown-like Ag8S core and an Ag10S16P8 meso-shell. The presence of the core induces symmetry breaking of the nanocluster from S8 to C4, and therefore endows the cluster with chirality.
Reference Key
tian2020agsptbbtpphchemical Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Tian, Fan;Chen, Rong;
Journal Chemical communications (Cambridge, England)
Year 2020
DOI
10.1039/c9cc10045h
URL
Keywords
amine-imine-exchange strategy morphological transformation orthogonal dynamic covalent self-assembly polymer nanocapsules and thin films

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