General Strategy for Synthesis of Ordered Pt3M Intermetallics with Ultrasmall Particle-size.

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ID: 92109
2020
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Abstract
Controllable synthesis of atomically ordered intermetallic nanoparticles (NPs) is crucial to obtain superior electrocatalytic performance for fuel cell reactions, but still remains arduous. Herein, we demonstrate a novel and general hydrogel-freeze drying strategy for the synthesis of reduced graphene oxide ( rGO ) supported Pt 3 M (M= Mn, Cr, Fe and Co etc.) intermetallic NPs (Pt 3 M/rGO-HF) with ultrasmall particle-size (about 3 nm) and dramatic monodispersity. The formation of hydrogel prevents the aggregation of graphene oxide and significantly promotes their excellent dispersion, while a freeze-drying can retain the hydrogel derived three-dimensionally (3D) porous structure and immobilize the metal precursors with defined atomic ratio on GO support during solvent sublimation, which is not afforded by traditional oven drying. The subsequent annealing process produces rGO supported ultra-small ordered Pt 3 M intermetallic NPs (~3 nm) due to confinement effect of 3D porous structure. Such Pt 3 M intermetallic NPs exhibit the smallest particle size among the reported ordered Pt-based intermetallic catalysts. A detailed study of the synthesis of ordered intermetallic Pt 3 Mn/rGO catalyst is provided as an example of a generally applicable method. This study provides an economical and scalable route for the controlled synthesis of Pt-based intermetallic catalysts, which can pave a way for the commercialization of fuel cell technologies.
Reference Key
zhang2020generalangewandte Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Zhang, Bentian;Fu, Gengtao;Li, Yutao;Liang, Lecheng;Grundish, Nicholas S;Tang, Yawen;Goodenough, John B;Cui, Zhiming;
Journal angewandte chemie (international ed in english)
Year 2020
DOI
10.1002/anie.201916260
URL
Keywords
oxygen reduction reaction intermetallic pt3m nanoparticles general strategy ultrathin particle-size uniform distribution

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