Controlling gas selectivity in molecular porous liquids by tuning the cage window size.

Clicks: 238
ID: 91043
2020
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Ranked #116 of 192 articles by views in angewandte chemie (international ed in english)

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Abstract
Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH4-selective, which is understood using 129Xe, 1H, and pulsed-field gradient NMR spectroscopy.
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egleston2020controllingangewandte Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Egleston, Benjamin;Luzyanin, Konstantin;Brand, Michael;Clowes, Rob;Briggs, Michael;Greenaway, Rebecca L;Cooper, Andrew;
Journal angewandte chemie (international ed in english)
Year 2020
DOI
10.1002/anie.201914037
URL
Keywords
adsorption selectivity porous liquids porous organic cages

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