Palladium-Catalyzed Synthesis of Benzophenanthrosilines by C-H/C-H Coupling through 1,4-Palladium Migration/Alkene Stereoisomerization.

Clicks: 301
ID: 89090
2020
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This article has not been analysed, so there is no overall score — reader engagement is measured and shown alongside.
AI Quality Assessment
Not analyzed
Readership in this journal
Emerging

Ranked #70 of 192 articles by views in angewandte chemie (international ed in english)

Most read Least read

Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 192 in total.

Mint this article as an NFT
Not yet minted

Create a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.

5 SUSD one-off · no wallet required
Sign in to mint
Abstract
A new and efficient synthesis of 8 H -benzo[ e ]phenanthro[1,10- bc ]silines from 2-((2-(arylethynyl)aryl)silyl)aryl triflates has been developed under palladium catalysis. The reaction mechanism has been experimentally investigated and a catalytic cycle involving a C-H/C-H coupling through a new mode of 1,4-palladium migration with concomitant alkene stereoisomerization has been proposed.
Reference Key
tsuda2020palladiumcatalyzedangewandte Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Tsuda, Tomohiro;Kawakami, Yuka;Choi, Seung-Min;Shintani, Ryo;
Journal angewandte chemie (international ed in english)
Year 2020
DOI
10.1002/anie.202000217
URL
Keywords
silicon palladium 1,4-migration c-h coupling π-conjugated compounds

Citations

No citations found. To add a citation, contact the admin at info@scimatic.org

Comments

No comments yet. Be the first to comment on this article.