Azido and Tetrazolo 1,2,4,5-Tetrazine N-Oxides.

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ID: 83180
2017
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Abstract
This study presents the synthesis and characterization of the oxidation products of 3,6-diazido-1,2,4,5-tetrazine (1) and 6-amino-[1,5-b]tetrazolo-1,2,4,5-tetrazine (2). 3,6-Diazido-1,2,4,5-tetrazine-1,4-dioxide was produced from oxidation with peroxytrifluoroacetic acid, and more effectively using hypofluorous acid, and 2 can be oxidized to two different products, 6-amino-[1,5-b]tetrazolo-1,2,4,5-tetrazine mono-N-oxide and di-N-oxide. These N-oxide compounds display promising performance properties as energetic materials.
Reference Key
chavez2017azidoangewandte Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Chavez, David E;Parrish, Damon A;Mitchell, Lauren;Imler, Greg H;
Journal angewandte chemie (international ed in english)
Year 2017
DOI
10.1002/anie.201612496
URL
Keywords
energetic materials azides tetrazole 1,2,4,5-tetrazine n-oxides

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