Separation and Recovery of Scandium from Sulfate Media by Solvent Extraction and Polymer Inclusion Membranes with Amic Acid Extractants.

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ID: 72821
2019
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Abstract
We report on the separation and recovery of scandium(III) from sulfate solutions using solvent extraction and a membrane transport system utilizing newly synthesized amic acid extractants. Scandium(III) was quantitatively extracted with 50 mmol dm-[,-di(2-ethylhexyl)aminocarbonylmethyl]glycine (D2EHAG) or -[,-di(2-ethylhexyl)aminocarbonylmethyl]phenylalanine (D2EHAF) in -dodecane at pH 2 and easily stripped using a 0.5 mol dm sulfuric acid solution. The extraction mechanisms of scandium(III) extraction with D2EHAG and D2EHAF were examined, and it was established that scandium(III) formed a 1:3 complex with both extractants (HR), that is, Sc(SO) + 1.5(HR) ⇄ Sc(SO)R(HR) + H + SO. The equilibrium constants of extraction were evaluated to be 4.87 and 9.99 (mol dm) for D2EHAG and D2EHAF, respectively. D2EHAG and D2EHAF preferentially extracted scandium(III) with a high selectivity compared to common transition metal ions under high acidic conditions (0 < pH ≤ 3). In addition, scandium(III) was quantitatively transported from a feed solution into a 0.5 mol dm sulfuric acid receiving solution through a polymer inclusion membrane (PIM) containing D2EHAF as a carrier. Scandium(III) was completely separated thermodynamically from nickel(II), aluminum(III), cobalt(II), manganese(II), chromium(III), calcium(II), and magnesium(II), and partially separated from iron(III) kinetically using a PIM containing D2EHAF as a carrier. The initial flux value for scandium(III) ( = 1.9 × 10 mol m s) was two times higher than that of iron(III) ( = 9.3 × 10 mol m s).
Reference Key
yoshida2019separationacs Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Yoshida, Wataru;Kubota, Fukiko;Baba, Yuzo;Kolev, Spas D;Goto, Masahiro;
Journal ACS omega
Year 2019
DOI
10.1021/acsomega.9b02540
URL
Keywords
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