Unusually Stable Triazine-based Organic Superstructures.

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ID: 72803
2016
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Ranked #162 of 192 articles by views in angewandte chemie (international ed in english)

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Abstract
Solid-state reactions have been rapidly gaining popularity in organic chemistry owing to their simplicity, efficiency, and selectivity compared to liquid-phase reactions. Herein, we describe the formation of superstructures through the solid-state reaction of an organic single-crystal. The superstructure of 5,5',5''-(1,3,5-triazine-2,4,6-triyl)triisophthalonitrile (TIPN) can be formed by cyclotrimerization of 1,3,5-tricyanobenzene (TCB) single crystals. The TIPN superstructure was confirmed by single crystal X-ray diffraction and visualized by transmission electron microscopy. The superstructure has hexagonally packed 1-dimensional (1D) channels along the crystal axis. Furthermore, the superstructure arises from interdigitated nitrile interactions in the crystal lattice, and thus has electron-beam tolerance and very high thermal stability.
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jung2016unusuallyangewandte Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Jung, Sun-Min;Kim, Dongwook;Shin, Dongbin;Mahmood, Javeed;Park, Noejung;Lah, Myoung Soo;Jeong, Hu Young;Baek, Jong-Beom;
Journal angewandte chemie (international ed in english)
Year 2016
DOI
10.1002/anie.201601807
URL
Keywords
interdigitation porous organic crystals single-crystals solid-state reactions superstructures

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