Forming a three-dimensional porous organic network via solid-state explosion of organic single crystals.

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ID: 72797
2017
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Abstract
Solid-state reaction of organic molecules holds a considerable advantage over liquid-phase processes in the manufacturing industry. However, the research progress in exploring this benefit is largely staggering, which leaves few liquid-phase systems to work with. Here, we show a synthetic protocol for the formation of a three-dimensional porous organic network via solid-state explosion of organic single crystals. The explosive reaction is realized by the Bergman reaction (cycloaromatization) of three enediyne groups on 2,3,6,7,14,15-hexaethynyl-9,10-dihydro-9,10-[1,2]benzenoanthracene. The origin of the explosion is systematically studied using single-crystal X-ray diffraction and differential scanning calorimetry, along with high-speed camera and density functional theory calculations. The results suggest that the solid-state explosion is triggered by an abrupt change in lattice energy induced by release of primer molecules in the 2,3,6,7,14,15-hexaethynyl-9,10-dihydro-9,10-[1,2]benzenoanthracene crystal lattice.
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bae2017formingnature Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Bae, Seo-Yoon;Kim, Dongwook;Shin, Dongbin;Mahmood, Javeed;Jeon, In-Yup;Jung, Sun-Min;Shin, Sun-Hee;Kim, Seok-Jin;Park, Noejung;Lah, Myoung Soo;Baek, Jong-Beom;
Journal Nature communications
Year 2017
DOI
10.1038/s41467-017-01568-3
URL
http://link.springer.com/article/10.1038/s41467-017-01568-3
Keywords
carbon dioxide methane hydrogen 3d cage-like networks gas uptake

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