Formation of CoS Nanobubble Hollow Prisms for Highly Reversible Lithium Storage.

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ID: 713
2016
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Ranked #47 of 192 articles by views in angewandte chemie (international ed in english)

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Abstract
Metal-organic frameworks (MOFs) have been intensively used as the templates/precursors to synthesize complex hollow structures for various energy-related applications. Herein we report a facile two-step diffusion-controlled strategy to generate novel MOFs derived hierarchical hollow prisms composed of Nanosized CoS bubble-like subunits. Uniform zeolitic imidazolate framework-67 (ZIF-67) hollow prisms assembled by interconnected nanopolyhedra are first synthesized via a transformation process. Afterwards, these ZIF-67 building blocks are converted into CoS bubble-like hollow particles to form the complex hollow prisms through a sulfidation reaction with an additional annealing treatment. When evaluated as an electrode material for lithium-ion batteries, the as-obtained CoS nanobubble hollow prisms show remarkable electrochemical performance with good rate capability and long cycle life.
Reference Key
yu2016formation Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Yu, Le;Yang, Jing Fan;Lou, Xiong Wen David;
Journal angewandte chemie (international ed in english)
Year 2016
DOI
10.1002/anie.201606776
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