tert-Butyl peroxide (TBHP)/KI-mediated dual C(sp)-H bond amination of arylamines with α-diazo carbonyls toward 1,2,4-benzotriazines.

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ID: 64047
2019
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Abstract
A new radical-induced dehydrogenative heterocyclization of arylamines with α-diazo carbonyls has been established under metal-free oxidative conditions, enabling two-fold C(sp2)-H bond amination to access a wide range of functionalized 1,2,4-triazine derivatives with generally good yields by combining KI/tert-butyl peroxide (TBHP). The present protocol features wide substrate scope, commercial accessibility, and mild reaction conditions. Mechanistic details of this radical process are rendered by conducting systematic theoretical calculations.
Reference Key
zhang2019tertbutylchemical Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Zhang, Tian-Shu;Zhang, Hongping;Fu, Rong;Wang, Jianyi;Hao, Wen-Juan;Tu, Shu-Jiang;Jiang, Bo;
Journal Chemical communications (Cambridge, England)
Year 2019
DOI
10.1039/c9cc07236e
URL
Keywords
non-doped thermally activated delayed fluorescence (tadf) triazine

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