trans-Bis(perchlorato-κO)tetrakis(1H-pyrazole-κN2)copper(II)

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ID: 64034
2008
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Ranked #207 of 280 articles by views in acta crystallographica section e

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Abstract
The title compound, [Cu(ClO4)2(C3H4N2)4], was obtained unexpectedly by the reaction of copper(II) perchlorate hexahydrate with equimolar amounts of 1-chloro-1-nitro-2,2,2-tripyrazolylethane in methanol solution. The crystal structure comprises octahedrally coordinated Cu2+ ions, located on an inversion centre, with four pyrazole ligands in the equatorial plane. The average Cu—N distance is 2.000 (1) Å. Two perchlorate ions are coordinated to copper in trans positions [Cu—O = 2.4163 (11) Å].
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zapolskii2008transbisperchlorato954otetrakis1hpyrazole954n2copperiiacta Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Zapol'skii, Viktor;Wagner, Thomas;Blaurock, Steffen;Kaufmann, Dieter E.;Edelmann, Frank T.;
Journal acta crystallographica section e
Year 2008
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