Pillaring of layered zeolite precursors with ferrierite topology leading to unusual molecular sieves on the micro/mesoporous border.

Tiklamalar: 337
ID: 632
2018
Makale Kalitesi ve Performans Metrikleri
Genel Kalite
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Yapay Zeka Kalite Degerlendirmesi
Analiz edilmedi
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Ranked #31 of 324 articles by views in Dalton transactions (Cambridge, England : 2003)

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Ozet
Layered zeolite materials with FER layer topology can produce various condensed and expanded structures including zeolite frameworks, FER and CDO, their interlayer expanded forms (IEZ), and organic-intercalated and pillared derivatives. This work concerns pillaring of the surfactant-swollen derivative with a gallery height of ca. 2.5 nm between layers by treatment with tetraethylorthosilicate (TEOS) at room and elevated temperatures. The materials obtained at 100 °C and higher showed unusual properties including 2 nm pores on the micro/mesoporous border and disordered layer packing indicated by the absence of distinct low angle interlayer peaks at d-spacing >3 nm (∼3° 2θ Cu Kα radiation) in the X-ray diffraction pattern (XRD). TEOS treatment at room temperature produced a pillared molecular sieve with the expected mesoporous characteristics, namely a pore size of around 3 nm and a high intensity low angle (001) peak at 2.3° 2θ, and a d-spacing of 3.8 nm, in the XRD. The characterization aiming to elucidate the nature of the obtained unusual products included gas adsorption isotherms, aberration corrected (C-corrected) Scanning Transmission Electron Microscopy (STEM) studies and Si solid state NMR. BET surface area values decreased with the temperature of TEOS treatment from approximately 1200 m g to ∼900 and 600 m g, at room temperature, 100 °C, and 120 °C, respectively. The Si solid state NMR revealed the presence of both Q ((SiO)SiOX, X = H or minus charge) and Q ((SiO)Si) centers giving separated signals up to the pillaring step. After pillaring at 100 °C and calcination, the nominal intensity ratios Q : Q were 2.17 and 2.61 but the signals were merged into one broad peak indicating the structural heterogeneity of Si-O coordination. The microscopy showed the presence of FER layers in the samples but the overall structure and composition were not well-defined. The observed unusual disorganization and possible partial degradation of layers during pillaring may result from the combination of high temperature, alkalinity (surfactant hydroxide) and siliceous composition of the layers. The obtained pillared products are of interest for the preparation of larger pore catalysts and sorbents or controlled drug delivery.
Referans Anahtari
roth2018pillaring Kullanarak makale yazarken otomatik alinti icin bu anahtari kullanin SciMatic Makale Yoneticisi veya Tez Yoneticisi
Yazarlar Wieslaw J Roth, Barbara Gil, Alvaro Mayoral, Justyna Grzybek, Aleksandra Korzeniowska, Martin Kubu, Wacław Makowski, Jiří Čejka, Zbigniew Olejniczak, Michal Mazur
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Dergi Dalton transactions (Cambridge, England : 2003)
Yil 2018
DOI
10.1039/c7dt03718j
URL
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