2-Methylsulfanyl-1H-perimidin-3-ium iodide
Clicks: 287
ID: 56949
2012
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Abstract
In the structure of the title salt C12H11N2S+·I−, the methylsulfanyl group of the cation is nearly coplanar with the perimidine rings, as indicated by the C—S—C—N torsion angles of 2.9 (5) and −177.2 (3)°, respectively. The (S)C—N bond lengths in the heterocyclic ring are approximately equal [1.325 (5) and 1.326 (6) Å] suggesting a degree of delocalization. In the crystal, cations and anions are linked via two discrete N—H...I hydrogen bonds, forming chains along the b axis.
| Reference Key |
ghorbani20122methylsulfanyl1hperimidin3iumacta
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|---|---|
| Authors | Ghorbani, Mohammad Hassan; |
| Journal | acta crystallographica section e |
| Year | 2012 |
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