3-Deoxyaconitine from the root of Aconitum Carmichaeli Debx.

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ID: 56946
2010
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Abstract
The title compound (systematic name: 8β-acetoxy-14α-benzoyloxy-N-ethyl-13β,15α-dihydroxy-1α,6α,16β-trimethoxy-4β-methoxymethyleneaconitane), C34H47NO10, is a typical aconitine-type C19-diterpenoid alkaloid, and was isolated from the roots of the Aconitum carmichaeli Debx. The molecule has an aconitine carbon skeleton with four six-membered rings and two five-membered rings, whose geometry is similar to these observed in other C19-diterpenoid alkaloids; both of five-membered rings have the envelope configurations and the six-membered N-containing heterocyclic ring displays a chair conformation. Intramolecular O—H...O hydrogen bonding occurs. Weak intermolecular C—H...O hydrogen bonding is observed in the crystal structure.
Reference Key
gao20103deoxyaconitineacta Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Gao, Feng;Zhu, Shou-An;Xiong, Shi-Jun;
Journal acta crystallographica section e
Year 2010
DOI
DOI not found
URL
http://scripts.iucr.org/cgi-bin/paper?S1600536810016922
Keywords
chemistry crystallography

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