1-Methyl-1H-2,1-benzothiazin-4(3H)-one 2,2-dioxide

Clicks: 165
ID: 56942
2008
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Abstract
In the crystal structure of the title compound, C9H9NO3S, there is distorted tetrahedral geometry around the S atom. The sulfonyl group is almost normal to the benzene ring, while the carbonyl O atom and methyl C atom are on opposite sides of this ring. The heterocyclic ring adopts a half-boat conformation with the S atom out of the plane. The molecules are dimerized by hydrogen bonding involving the benzene ring and the sulfonyl group. These dimers are linked to each other in the same way. There is an intramolecular hydrogen bond between a methyl C—H group and a sulfonyl O atom, and a π–π interaction between the aromatic rings of two dimers at a centroid-to-centroid distance of 3.6373 (13) Å.
Reference Key
arshad20081methyl1h21benzothiazin43honeacta Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Arshad, Muhammad Nadeem;Siddiqui, Waseeq Ahmad;Khan, Islam Ullah;Shafiq, Muhammad;Tahir, M. Nawaz;
Journal acta crystallographica section e
Year 2008
DOI
DOI not found
URL
http://scripts.iucr.org/cgi-bin/paper?S1600536808003498
Keywords
chemistry crystallography

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