6-Bromo-1,3-di-2-propynyl-1H-imidazo[4,5-b]pyridin-2(3H)-one

Clicks: 122
ID: 52651
2010
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Abstract
The room-temperature reaction of propargyl bromide and 6-bromo-1,3-dihydroimidazo[4,5-b]pyridin-2-one in dimethylformamide yields the title compound, C12H8BrN3O, which features nitrogen-bound propynyl substituents. The imidazopyridine fused ring is almost planar (r.m.s. deviation = 0.011 Å); the propynyl chains point in opposite directions relative to the fused ring. One acetylenic H atom is hydrogen bonded to the carbonyl O atom of an inversion-related molecule, forming a dimer; adjacent dimers are linked by a second acetylene–pyridine C—H...N interaction, forming a layer motif.
Reference Key
dahmani20106bromo13di2propynyl1himidazo45bpyridin23honeacta Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Dahmani, S.;Haoudi, A.;Capet, F.;Essassi, El Mokhtar;Ng, Seik Weng;
Journal acta crystallographica section e
Year 2010
DOI
DOI not found
URL
http://scripts.iucr.org/cgi-bin/paper?S1600536810007701
Keywords
chemistry

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