1,1-Dimethylbiguanidium(2+) dinitrate

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ID: 52647
2012
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Abstract
In the crystal structure of the title compound, C4H13N52+·2NO3−, the main intermolecular interactions are the N—H...O hydrogen bonds between the cationic amino groups and the O atoms of the nitrate ions. All amino H atoms and nitrate O atoms are involved in the three-dimensional hydrogen-bond network. There are two graph-set motifs R22(8), which include the amino groups connected to the N atoms in the biguanide 3-, 4- and 5-positions, and the O atoms of a nitrate ion. They are extended along the a axis. An O atom of the second nitrate ion is involved in a graph-set motif C(4) that is a part of a helix-like N—H...O...H—N—H...O... chain oriented along the b axis. There are also two weak C—H...O interactions in the crystal structure.
Reference Key
fridrichovamp225201211dimethylbiguanidium2acta Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Fridrichová, Michaela;Císařová, Ivana;Němec, Ivan;
Journal acta crystallographica section e
Year 2012
DOI
DOI not found
URL
http://scripts.iucr.org/cgi-bin/paper?S1600536811051105
Keywords
chemistry

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