Fused rings with N-oxide and -NH: good combination for high density and low sensitivity energetic materials.

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ID: 4706
2019
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Ranked #27 of 184 articles by views in Chemical communications (Cambridge, England)

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Abstract
Oxidation reactions of 3,6-diamino-1,2,4-triazolo[4,3-b][1,2,4,5]tetrazine give four N-oxide compounds. Because of the presence of an amino group and the N-oxide moiety, these compounds are extensively hydrogen bonded. Resulting from π-π stacking interactions between the fused rings, compounds 1-3 are impact and friction insensitive, are thermally stable and have good density.
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hu2019fusedchemical Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Hu, Lu;Yin, Ping;Imler, Gregory H;Parrish, Damon A;Gao, Haixiang;Shreeve, Jean'ne M;
Journal Chemical communications (Cambridge, England)
Year 2019
DOI
10.1039/c9cc04496e
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