Continuous-feed carbonation of waste incinerator bottom ash in a rotating drum reactor.

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ID: 33142
2019
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Ranked #128 of 145 articles by views in waste management (new york, ny)

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Abstract
Carbonation is a key process in the aging of waste incinerator bottom ash (BA). The reaction with CO decreases the BA alkalinity and lowers the leachability of amphoteric trace metals. Passive ageing over several months is usually performed in intermittently mixed BA heaps. Here we aimed at accelerating the process in a rotating drum reactor continuously fed with the BA and the reactant gas (10 vol-% CO, volumetric flow rate 60 L/min). In one test, the gas was heated and humidified. Since carbonation depends on the specific CO-supply, experiments were conducted at varied BA residence time (60, 80, and 100 min). Residence time was calculated by mass balancing and confirmed by the breakthrough time of two tracers. Leachates and solid phase properties of the treated BA served to evaluate the carbonation performance. The residence time of BA could be adequately controlled by the reactor loading and feed rate. A residence time of 80 min was sufficient to reduce the BA leachability such as to comply with the German regulatory standards for non-hazardous waste, whereas the untreated BA was hazardous waste. Decreased alkalinity was indicated by lower leachate pH and Ca(OH) contents of the BA as compared to the input. Leachate concentrations of amphoteric trace metals (Pb, Zn, Cu) decreased by at least one order of magnitude while oxyanions became slightly more mobile upon carbonation. In view of relatively short residence times and stable process performance, the rotating drum reactor seems promising for a full-scale implementation of BA carbonation.
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bruck2019continuousfeedwaste Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Brück, Felix;Ufer, Kristian;Mansfeldt, Tim;Weigand, Harald;
Journal waste management (new york, ny)
Year 2019
DOI
S0956-053X(19)30545-8
URL
Keywords Keywords not found

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