Hybrid Noble-Metals/Metal-Oxide Bifunctional Nano-Heterostructure Displaying Outperforming Gas-Sensing and Photochromic Performances.
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ID: 32939
2018
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Abstract
As nanomaterials are dominating 21st century's scene, multiple functionality in a single (nano)structure is becoming very appealing. Inspired by the Land of the Rising Sun, we designed a bifunctional (gas-sensor/photochromic) nanomaterial, made with TiO whose surface was simultaneously decorated with copper and silver (the Cu/Ag molar ratio being 3:1). This nanomaterial outperformed previous state-of-the-art TiO-based sensors for the detection of acetone, as well as the Cu-TiO-based photochromic material. It indeed possessed splendid sensitivity toward acetone (detection limit of 100 ppb, 5 times lower than previous state-of-the-art TiO-based acetone sensors), as well as reduced response/recovery times at very low working temperature, 150 °C, for acetone sensing. Still, the same material showed itself to be able to (reversibly) change in color when stimulated by both UV-A and, most remarkably, visible light. Indeed, the visible-light photochromic performance was almost 3 times faster compared to the standard Cu-TiO photochromic material-that is, 4.0 min versus 10.8 min, respectively. It was eventually proposed that the photochromic behavior was triggered by different mechanisms, depending on the light source used.
| Reference Key |
tobaldi2018hybridacs
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| Authors | Tobaldi, David Maria;Leonardi, Salvatore Gianluca;Movlaee, Kaveh;Lajaunie, Luc;Seabra, Maria Paula;Arenal, Raul;Neri, Giovanni;Labrincha, João António; |
| Journal | ACS omega |
| Year | 2018 |
| DOI |
10.1021/acsomega.8b01508
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| URL | |
| Keywords | Keywords not found |
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