Controlling site-selectivity in C—C bond formation of cyclohexa-2,4-dienones and ortho -quinones

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ID: 329176
2026
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Abstract
Abstract C–C bond formation involving phenol-derived oxidative intermediates has steadily advanced in recent years. This review focuses on the site-selectivity of C–C bond formation in cyclohexa-2,4-dienones and ortho-quinones generated via oxidative transformations of phenols. These transformations provide efficient access to multiply substituted catechols, which are important structural motifs in the pharmaceutical industry. By summarizing substituent effects and reaction conditions, this review establishes guidelines for accessing a broad range of catechols via site-selective C–C bond formation.
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openalex_W7213639446 Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Riichi Hashimoto, Yoshinari Swama
Journal phytochemistry letters
Year 2026
DOI
10.1093/chemle/upag192
URL
https://doi.org/10.1093/chemle/upag192
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