A Porphyrin Cage Formed via Imine Bonds that Encapsulates Fullerenes

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ID: 329148
2026
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Abstract
Abstract A readily accessible imine-linked porphyrin cage was constructed in one step and shown to encapsulate C60 and C70. Fullerenes can be incorporated either during cage formation or by post-synthetic uptake, highlighting the adaptability of dynamic covalent assembly. Single-crystal X-ray diffraction of the C60 complex revealed the guest within the cavity and close porphyrin–C60 contacts.
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Authors Shota Higashihata, Takumi Torisawa, Haruto Togashi, Ryota Yamada, Yosuke Hosoya, Kosuke Sugawa, Joe Otsuki
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Journal phytochemistry letters
Year 2026
DOI
10.1093/chemle/upag187
URL
https://doi.org/10.1093/chemle/upag187
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