Syntheses of Nostodione A and Half Scytonemins

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ID: 326862
2026
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Abstract
Syntheses of nostodione A and half scytonemins have been achieved. Nostodione A was synthesized by oxidation of a compound possessing the 3,4-dihydrocyclopenta[b]indol-2(1H)-one skeleton, which was employed in our scytonemin synthesis. Half scytonemins have been synthesized from the same intermediate by the reaction sequence including reduction to indoline, Pd (0)-catalyzed arylation at the α position of the ketone, and oxidation of both the side chain and the tricyclic core structure. UV-Vis spectra of half scytonemins were compared with that of scytonemin, a UV-absorbing cyanobacterial sheath pigment.
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Authors Yutaro Udagawa, Seijiro Hosokawa
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Journal bioscience biotechnology and biochemistry
Year 2026
DOI
10.1093/bbb/zbag130
URL
https://doi.org/10.1093/bbb/zbag130
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