Nitrogen-directed C–H borylation catalyzed by polysaccharide-stabilized ruthenium nanoparticles

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ID: 326750
2026
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Abstract
Abstract Polysaccharide-supported ruthenium catalysts (Ru/polysaccharide) efficiently promoted the regioselective C–H borylation of diverse N(sp2)-containing substrates. Ru/cellulose was highly active for aromatic C(sp2)–H borylation, whereas Ru/chitin preferentially functionalized aliphatic C(sp3)–H bonds. These catalysts were readily prepared from commercially available polysaccharides and ruthenium(III) chloride, providing stable sources of Ru(0) species. The Ru/polysaccharide prepared in this manner may serve as a precursor that gradually releases catalytically competent ruthenium nanoparticles into solution.
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Authors Yuna Maeda, Noeru Kaneda, Miki Murata
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Journal phytochemistry letters
Year 2026
DOI
10.1093/chemle/upag157
URL
https://doi.org/10.1093/chemle/upag157
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