Nitrogen-directed C–H borylation catalyzed by polysaccharide-stabilized ruthenium nanoparticles

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ID: 326750
2026
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Abstract
Abstract Polysaccharide-supported ruthenium catalysts (Ru/polysaccharide) efficiently promoted the regioselective C–H borylation of diverse N(sp2)-containing substrates. Ru/cellulose was highly active for aromatic C(sp2)–H borylation, whereas Ru/chitin preferentially functionalized aliphatic C(sp3)–H bonds. These catalysts were readily prepared from commercially available polysaccharides and ruthenium(III) chloride, providing stable sources of Ru(0) species. The Ru/polysaccharide prepared in this manner may serve as a precursor that gradually releases catalytically competent ruthenium nanoparticles into solution.
Reference Key
openalex_W7204465694 Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Yuna Maeda, Noeru Kaneda, Miki Murata
Journal phytochemistry letters
Year 2026
DOI
10.1093/chemle/upag157
URL
https://doi.org/10.1093/chemle/upag157
Keywords Keywords not found

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