Ir/NNSi-Potassium tert -Butoxide Catalyst System for C(sp3)–H Borylation Using Equimolar Amounts of Substrate and Bis(pinacolato)diboron
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ID: 325445
2026
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Abstract
Abstract An Ir/NNSi-catalyzed alkyl C(sp3)–H borylation using equimolar amounts of substrate and bis(pinacolato)diboron is described. The performance of the Ir/NNSi catalyst was enhanced by the addition of a catalytic amount of KOtBu. Under these conditions, chemoselective C(sp3)–H borylation was achieved for a range of alkyl compounds, including THP-protected alkanols and ethylene glycol acetal-protected 5-nonanone.
| Reference Key |
openalex_W7203758942
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|---|---|
| Authors | Takeru Torigoe, Tomoki Kawasaki, Toshimichi Ohmura |
| Journal | phytochemistry letters |
| Year | 2026 |
| DOI |
10.1093/chemle/upag166
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| URL | |
| Keywords | Keywords not found |
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