Synthetic Studies on Leptolyngbyalides A–C: Stereoselective Synthesis of the C1–C15 Fragment
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ID: 323251
2026
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Abstract
Abstract We describe herein a stereoselective synthesis of the C1–C15 fragment of leptolyngbyalides A–C. A stereochemically modular synthesis of the C4–C12 domain harboring the configurationally unassigned C5, C7, and C9 stereogenic centers was achieved by taking advantage of chiral auxiliary-assisted diastereoselective reactions. Subsequent transformations including an aldol coupling, a Narasaka–Prasad reduction, and a Suzuki–Miyaura coupling completed the synthesis of the C1–C15 fragment, corresponding to an open-chain form of the macrocyclic skeleton of of leptolyngbyalides A–C.
| Reference Key |
openalex_W7172295398
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|---|---|
| Authors | Keisuke Murata, Haruhiko Fuwa |
| Journal | phytochemistry letters |
| Year | 2026 |
| DOI |
10.1093/chemle/upag153
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| URL | |
| Keywords | Keywords not found |
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