AgSbF6-Promoted Divergent Synthesis of Highly Substituted Indene Derivatives from Methylenecyclopropane and Aroyl Chlorides
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ID: 321705
2026
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Abstract
Abstract When 2,2-diphenylmethylenecyclopropane was reacted with aroyl chlorides in 1,2-dichloroethane (DCE) at 35 °C in the presence of AgSbF6, indene derivatives were obtained through a cascade process involving cyclopropane ring-opening and five-membered-ring formation. Electron-rich and moderately electron-deficient aroyl chlorides afforded 2,3-disubstituted 1H-indene derivatives, whereas strongly electron-deficient or sterically demanding aroyl chlorides selectively furnished 2,3,6-trisubstituted 1H-indene derivatives. This AgSbF6-promoted divergent reaction provides efficient and selective access to highly substituted indene derivatives.
| Reference Key |
openalex_W7169854133
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| Authors | X D Wang, Yun Wang, Junwen Ye, Yasuyuki Ura, Yasushi Nishihara |
| Journal | phytochemistry letters |
| Year | 2026 |
| DOI |
10.1093/chemle/upag148
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| URL | |
| Keywords | Keywords not found |
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