Gel polymer electrolyte comprising a highly concentrated lithium salt/sulfolane electrolyte and partially fluorinated tetra-arm polymer
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ID: 321385
2026
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Abstract
Abstract A gel polymer electrolyte (GPE) with enhanced mechanical strength and a high Li-ion transference number (tLi+) was developed via the crosslinking of tetra-arm poly(2,2,3,3-tetrafluoropropyl acrylate) in a sulfolane-based highly concentrated electrolyte ([Li(SL)3][TFSA]). The high tLi+ (0.64) was attributed to interactions between the fluorinated side-chain protons and TFSA anions. Moreover, rheological analysis indicated a low tan δ. The GPE showed oxidation stability up to 4.5 V and stable Li deposition/dissolution, highlighting its potential for battery applications.
| Reference Key |
openalex_W7169603002
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|---|---|
| Authors | Riko Sakakieda, Kazuki Miyagawa, Hisashi Kokubo, Ryoichi Tatara, Kaoru Dokko |
| Journal | phytochemistry letters |
| Year | 2026 |
| DOI |
10.1093/chemle/upag147
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| URL | |
| Keywords | Keywords not found |
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