Interchangeable Thermoresponsive Behavior of Adamantane-Modified Cellulose through Cyclodextrin Complexation

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ID: 318960
2026
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Abstract
Abstract Interchangeable control of polymer functions on a single polymer backbone is an attractive concept but remains highly challenging. In this study, adamantane-modified cellulose (Ad-cellulose) was developed as a supramolecular polymer platform for interchangeable thermoresponsive behavior through cyclodextrin (CD) complexation. Water-insoluble Ad-cellulose became soluble through complexation with hydroxypropyl-β-cyclodextrin (HP-β-CD) or permethylated β-cyclodextrin (Me-β-CD), whereas only the Me-β-CD system exhibited thermoresponsive aggregation at elevated temperature. These findings provide a new supramolecular design strategy for polymer systems with interchangeable functionality.
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openalex_W7166355332 Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Sooyeon Noh, Akihide Sugawara, Yoshinori Takashima, Hiroshi Uyama
Journal phytochemistry letters
Year 2026
DOI
10.1093/chemle/upag138
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