Cleavage of Si–O–Si Bonds with Alcohols Catalyzed by p -Toluenesulfonic Acid: Synthesis of Monoalkoxysilanes and Computational Mechanistic Study
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ID: 318055
2026
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Abstract
Abstract A sustainable strategy for synthesizing monoalkoxysilanes was developed via Si–O–Si bond cleavage of siloxanes using p-toluenesulfonic acid (TsOH) as a catalyst. The reaction proceeded without a metal catalyst or base under ambient conditions, with water as the only by-product. Various disiloxanes were efficiently converted to the corresponding monoalkoxysilanes. Furthermore, we proposed a plausible reaction pathway through a comprehensive approach combining automated reaction pathway exploration using the Global Reaction Route Mapping (GRRM) and Artificial Force-Induced Reaction (AFIR).
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| Authors | Nobuki Katayama, Yuuki Tanioka, Yuzuki Shinohara, Seiya Suzuki, Shinya Nakamura, Satoshi Maeda, Yasushi Obora |
| Journal | phytochemistry letters |
| Year | 2026 |
| DOI |
10.1093/chemle/upag125
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| URL | |
| Keywords | Keywords not found |
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