Introduction of polymerizable group at both ends of polyester and synthesis of network polymer containing polyester

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ID: 317569
2026
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Abstract
Abstract Base-catalyzed transesterification of cyclic polyester with diglycidyl phthalate affords polyester with an epoxy group at both ends, while similar transesterification with bis(4-vinylbenzyl) phthalate affords polyester with a styryl group at both ends. These polyesters work as cross-linkers. Polyester-network-containing polystyrene gel, obtained by the radical copolymerization of styrene and the latter cross-linker, is converted to a soluble polymer by transesterification with poly(ε-caprolactone).
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Authors Takayoshi Katoh, Ryouichi Okabayashi, Yoshihiro Ohta, Tsutomu Yokozawa
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Journal phytochemistry letters
Year 2026
DOI
10.1093/chemle/upag120
URL
https://doi.org/10.1093/chemle/upag120
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