Hydrogenation of Nitrobenzene to Aniline through Photocatalytic Reduction over Pt/BiVO4 under Visible Light
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ID: 316867
2026
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Abstract
Abstract Bismuth vanadate (BiVO4), a visible-light-responsive photocatalyst, was applied to the hydrogenation of nitrobenzene to aniline without H2 gas using Pt-loaded BiVO4 (Pt/BiVO4) in 2-propanol under visible light. 2-Propanol served as both solvent and hole scavenger. Slight conversion in the dark suggested that Pt/BiVO4 also functions as a thermal catalyst, unlike Pt/TiO2. This system enabled chemoselective reduction of halogenated nitrobenzenes to the corresponding anilines in high yields without dehalogenation under mild hydrogen-free conditions.
| Reference Key |
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| Authors | Kotomi Maruyama, Manami Hara, Daisuke Kozaki, Fumito Fujishiro, Shoya Oda, Atsuhiro Tanaka, Hiroshi Kominami, Masataka Ohtani, Ayumu Onda, Kazuya Imamura |
| Journal | phytochemistry letters |
| Year | 2026 |
| DOI |
10.1093/chemle/upag115
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| URL | |
| Keywords | Keywords not found |
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