A Supramolecular Framework Based on a Seven-Coordinate Sn(II) Mononuclear Complex

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ID: 316452
2026
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Abstract
Abstract We report the preparation and structural characterization of a novel mononuclear Sn(II) complex, [Sn(HBA)2(H2O)3]·7H2O (1), synthesized from Sn2+ ion and bromanilic acid (H2BA). Complex 1 has a rare seven-coordinate geometry among Sn(II)-based complexes. In the crystal structure, intermolecular π–π interactions and hydrogen bonding result in helical columnar assemblies, which further organize into a supramolecular three-dimensional framework structure with capsule-shaped voids.
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openalex_W7164049373 Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Keisuke Ishikawa, Hirokazu Kobayashi, Kazuya Otsubo
Journal phytochemistry letters
Year 2026
DOI
10.1093/chemle/upag109
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