Total synthesis and stability analysis of natural diacyl-type tuliposides and their non-natural isomers
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ID: 316440
2026
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Abstract
Abstract Tuliposides (Pos), major secondary metabolites in tulip, are classified into monoacyl- and diacyl-type compounds. Herein, we report the first total synthesis of naturally occurring diacyl-type PosD and PosF and their isomers diOH-PosD and isoPosF, respectively, from D-glucose in five steps. Under neutral conditions, the non-natural Pos isomers were significantly less stable than their natural counterparts.
| Reference Key |
openalex_W7164025940
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|---|---|
| Authors | Yasuo Kato, Kaito Sano, Taiji Nomura |
| Journal | bioscience biotechnology and biochemistry |
| Year | 2026 |
| DOI |
10.1093/bbb/zbag085
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| URL | |
| Keywords | Keywords not found |
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