Thiophene-Flanked Quinoidal Naphthodipyrrolidones for Small-Bandgap Semiconducting Oligomers and Polymers
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ID: 316320
2026
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Abstract
Abstract Small-bandgap semiconducting oligomers and polymers composed of quinoidal naphtho[1,2-b:5,6-b']dipyrrol-2,7-dione acceptor units and oligothiophene donor units were synthesized. Comparison with a phenyl-substituted reference showed that flanking thiophene units adjacent to the highly π-extended quinoidal core are crucial for efficient donor–acceptor interactions, leading to near-infrared absorption, small bandgaps down to 0.97 eV, and ambipolar carrier transport.
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| Authors | Shunnosuke Kurita, Kohsuke Kawabata, Kazuo Takimiya |
| Journal | phytochemistry letters |
| Year | 2026 |
| DOI |
10.1093/chemle/upag112
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| URL | |
| Keywords | Keywords not found |
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