Recent Progress in Semiconducting Block Copolymers Suited for Organic Photovoltaics

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ID: 315449
2026
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Abstract
Abstract Recent advances in organic photovoltaic (OPV) devices have pushed power conversion efficiencies beyond 20%; however, the precise control of bulk heterojunction morphology remains a critical challenge that urgently needs to be addressed. In this Highlight Review, we summarize recent research progress regarding semiconducting block copolymers in OPV applications, with particular emphasis on bottom-up polymer synthesis strategies. We describe the development of condensative chain polymerization and nonstoichiometric polycondensation systems, which enable the synthesis of structurally well-defined π-conjugated polymers and block copolymers. Furthermore, we discuss their applications as compatibilizers, single-component photoactive materials, and stretchable semiconducting polymers. These approaches provide new strategies for controlling nanoscale phase-separated structures and improving both device performance and mechanical durability. This review highlights the potential of semiconducting block copolymers as key materials for next-generation OPV technologies.
Reference Key
openalex_W7163052057 Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Tomoya Higashihara, Teruma Mikata, He Sun, Chu-Chen Chueh
Journal phytochemistry letters
Year 2026
DOI
10.1093/chemle/upag104
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