Synthesis, Structure, and Reactivity of a Phenanthroline–Iminoquinone Ligand

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ID: 315140
2026
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Abstract
Abstract A phenanthroline–iminoquinone ligand (1), incorporating a redox-active o-iminoquinone moiety into an N,N’-chelating 1,10-phenanthroline framework, was synthesized. Its structural, photophysical and electrochemical properties were investigated by experimental and computational analyses. The N,N’-chelating properties of 1 toward the Pd(II) center was confirmed by single-crystal X-ray diffraction of the corresponding Pd complex, in which the N-aryl imine moiety was found to isomerize to an indoline unit.
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Authors H. Miyabe, Tomhiro Iwai, Jun Terao
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Journal phytochemistry letters
Year 2026
DOI
10.1093/chemle/upag100
URL
https://doi.org/10.1093/chemle/upag100
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