Surfactant-assisted fabrication of particle assemblies altering the adsorption-induced structural changes of flexible MOFs

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ID: 313897
2026
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Abstract
Abstract The structural flexibility of metal–organic frameworks is influenced not only by composition and topology but also by particle aggregation states. Here we investigated the flexibility of MOF assemblies fabricated by a simple surfactant-assisted method without specialized equipment. The structural changes of [Cu(NMe2-ipa)] upon CO2 adsorption were suppressed in a regularly oriented monolayer assembly, whereas those in a randomly oriented multilayer assembly were similar to bulk powders, demonstrating that particle assembly is a practical technique for tuning MOF flexibility.
Reference Key
openalex_W7160716163 Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Kohei Negita, Shinpei Kusaka, Hiroaki Iguchi, Ryotaro Matsuda
Journal phytochemistry letters
Year 2026
DOI
10.1093/chemle/upag065
URL
https://doi.org/10.1093/chemle/upag065
Keywords Keywords not found

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