On the formation of silver silicate

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Abstract
BUT very little seems to have been done with regard to the formation of silicate of silver in the wet way.In Gmelin-Kraut's Inorganic Ohemistry, vol.iii, p. 970, the following statement is made :-" A solution of Ag.O in 2(HF)SiF., evaporated to the consistenc'y of a s'yrup, deposits hydroscopic crystals of 2AgF.SiF.+4H,O.Out of a solution of this compound, ammonia precipitates a yellow basic salt, if added in small quantities.An excess of ammonia precipitates silicate of silver."A like statement is made by Berzelius-Lehrb.d.Ohemie; Dresden, 1836, vol.iv, p. 629.With the exception of a paper by Dr. M. W. Iles,* nothing seems to have been done in this direction since then.With regard to the production of silver silicate in the wet way, Dr. !les merely repeated the above experiment, without making any analysis of the precipitate.The method I have used is so simple that it seems strange that it has not been used before.The reaction made use of was:Na,SiO,+2AgNO,=Ag,SiO,+2NaNO,.The solution of N a,SiO, was made by fusing together N a,OO.and SiO" and dissolving the mass ill water.The amount of SiO,
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Authors J. D. Hawkins
Journal american journal of science
Year 1890
DOI
10.2475/ajs.s3-39.232.311
URL
https://doi.org/10.2475/ajs.s3-39.232.311
Keywords Keywords not found

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