Contributions to chemistry from the laboratory of the Lawrence Scientific

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Abstract
On the relations of hyposulphite of soda to certa£n metallz'c oa:yds.THE employment of hyposulphite of soda as an analytical reagent was first suggested by Himly,' who in a short paper, intended only as a preliminary notice, pointed out the relations of this salt to solutions of arsenic, antimony, copper and platinum, and suggested its use as a general reagent in place of sulphydric acid.Himly's paper attracted little attention and was soon forgotten.The subject was again taken up at about the same time by VohI' and Slater S who appear to have been unacquainted with Himly's results.Vohl's investigation embraces the action of the hyposulpbite upon solutions of arsenic, antimony, tin, copper, mercury, silver, gold, platinum, lead, bismuth, and cadmium.Slater studied the action of tbe salt upon solutions of chromium in the form of chromic acid, arsenic, antimony, copper, bismuth, lead, and mercury, as well as upon ferridcyanid, ferrocyanid, and cyanid of potassium, and upon sulphocyanid of iron and h;rpermanganate of potash.The results obtained by these chemISts differ in some partioulare, especially as regards eopper and lead.More recently Chancel 4 has employed the hyposulphite for the separation of alumina from iron, and Stro-
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Authors Wolcott Gibbs
Journal american journal of science
Year 1864
DOI
10.2475/ajs.s2-37.111.346
URL
https://ajsonline.org/article/62304.pdf
Keywords Keywords not found

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