Determination of delta H of reaction from experimental pressure-temperature curves
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ID: 302810
1965
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Abstract
The plotting of experimentally determined crystal-gas equilibria in terms of log 10 fugacity and reciprocal temperature can give the delta H of reaction only if a correction is made for the effect of pressure on the solid phases. At pressures of more than two or three kilobars this correction is large and may change the value of the derived heat of reaction by a factor of two or more.
| Reference Key |
openalex_W2333191436
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|---|---|
| Authors | Philip M. Orville, H. J. Greenwood |
| Journal | american journal of science |
| Year | 1965 |
| DOI |
10.2475/ajs.263.8.678
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| URL | |
| Keywords | Keywords not found |
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