On caesium-mercuric halides

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Abstract
study of these compounds seems desirable since very little work has been dOlle in tllis direction, and therefore the present investigatioll of the cmsium-mercuric chlorides, bromides and iodides has been undertaken,The following is a complete list of the previously described mercnl"ic double-halides containing the alkali-metals and ammonium, as fat' as I have been able to find them: Na,HgOl, NH,HgOl, RbHg,OI, Rh,llgCJ, RbH[!OI, KHg,CI., 21-1,0 OS,HgOl, KI-T"B,' (N H.),IIgB,', NI(iIg•bJ".tlI,O K,HgBr, KH~OI3' H,O (NH,),Hg,OI.' 4IJ,O Na rIpI KHgl~,',.IIp K,I'Iil, ' NnHgOI" ItH,O (NH.),fIgOJ"Hp NH,Ifgl,.l..l-II,O (NH.),Hg"OI20K,IIgCI" H,O KHg1, , l~H,O RhnH~CI ,2H.0 (NHS,Hg-I" aI-1,OThe gt'eater 11 umbel' of these art'hlnge themsel ves in to two types with varying water of Ct'yst:tllizatiol1 01' witll none, There are two compounds of a third type, while the two remaining, more com plicated salts, stand alone.The last two were described by Holmes.* An effort has been made t.o make the examination of the cresiutn-l1lercllric salts vet'y complete, bnt it is not safe to say that every possible componnd has been prepared, fOl' negative results at'e uncertain, It will lIOt be necessat'y to describe the unsuccessful experiments whet'e ttlixtUl'es or uncertain pl'Oducts were ohtained, It is sufticient to say that othet' double-halides were repeatedly looked for in every' direction, and evetT indication of a new salt was followed I1p until a homogeneous product was obtained and analyzed.The following table gives a list of the salts that are to be described.One of them, O;;,IIgOI" has alt'eady been prepal'ecl by Godefftooy, t 1.Cs,HgCl 5 Cs IIo'Br
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Authors H. L. Wells
Journal american journal of science
Year 1892
DOI
10.2475/ajs.s3-44.261.221
URL
https://doi.org/10.2475/ajs.s3-44.261.221
Keywords Keywords not found

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