On a series of caesium trihalides; including their crystallography

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Abstract
IN the course of some experiments with caesium compouuds, bromine was added to a concentrated solution of caesium chloride with an astonishing result.There was instantly formed a bright yellow precipitate, so dense as to nearly solidify the liquid.The substance readily dissolved on warming the liquid, and, on cooling it, large crystals of a yellowish-red color were formed which were found to be OsOlBr •.In view of the fact that KI, was already known,-* this dis• covery made it probable that a series of caesium trihalides could be obtained.An attempt was accordingly made to prepare each of the fol1owing possible members of such a series containing chlorine, bromine and iodine.1. CsI, R. CsCl,! 2. CsBrI, 7. CsBr, 3. CsBr,I e. CsClEr, 4. [CsCll,] 9. CsCI,Br 5. CsClErI 10.
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Authors H. L. Wells, S. L. Penfield
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Journal american journal of science
Year 1892
DOI
10.2475/ajs.s3-43.253.17
URL
https://doi.org/10.2475/ajs.s3-43.253.17
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