Mean molal stoichiometric activity coefficients of alkali halides and related electrolytes in hydrothermal solutions

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ID: 295884
1984
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Abstract
Activity coefficients measured for NaCl at 325 degrees C and 350 degrees C and for KCl and CaCl 2 from 200 degrees C to 350 degrees C. Vapor pressures were converted to osmotic coefficients, and these osmotic coefficients were fit to both the Lietzke-Stoughton and Pitzer equations. Parameters for these salts and others (NaBr, NaI, NaHS, KBr, KI, LiCl, LiBr, and LiI), for which literature data exist, were tabulated. A simple model is presented that factors the activity coefficient into three parts corresponding to long-range electrostatic ion-ion interactions, hydration, and association; this reproduces experimental values with reasonable accuracy.--Modified journal abstract.
Reference Key
openalex_W1993093935 Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Scott A. Wood, David A. Crerar, Susan L. Brantley, M. Borcsik
Journal american journal of science
Year 1984
DOI
10.2475/ajs.284.6.668
URL
https://doi.org/10.2475/ajs.284.6.668
Keywords Keywords not found

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