Structure-Function Relations for Gravimetric and Volumetric Methane Storage Capacities in Activated Carbon.

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ID: 27931
2018
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Abstract
The complex structure of activated carbon can be described as a three-dimensional network of graphene layers oriented in random directions. In this work, we propose a new model of the microporous structure, taking into account the degree of activation. We derive a structural relation between porosity, skeletal density, specific surface area, and the number of graphitic blocks per unit volume. In addition, we present a new approach to evaluate the interdependency between porosity and specific surface area by combining high-resolution scanning transmission electron microscopy and subcritical nitrogen adsorption. Finally, we propose a structural metric that predicts the relation between the volumetric storage capacity and the gravimetric storage capacity of supercritical methane at room temperature.
Reference Key
romanos2018structurefunctionacs Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Romanos, Jimmy;Dargham, Sara Abou;Prosniewski, Matthew;Roukos, Roy;Barakat, Fatima;Pfeifer, Peter;
Journal ACS omega
Year 2018
DOI
10.1021/acsomega.8b02233
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Keywords Keywords not found

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